Katarina Zimmer put vinegar to the test as a cleaning product and discovered a wide range of benefits, for people and the planet.

A few months ago in my new Berlin apartment, my toilet and I were at war. No amount of scrubbing or toilet cleaner would evict the limescale coating inside. Frustrated, I turned to Google and stumbled across a page recommending vinegar – something that the previous inhabitant had left behind in abundance. After dropping two tablespoons full of "Essigessenz" – essentially concentrated vinegar – into the toilet and waiting for half an hour, I scrubbed and the limescale came off in a moment.

Since then, I've enthusiastically used vinegar to rid my world of limescale. I've found it even more effective than my regular kitchen spray cleaner for getting my sink sparkling. That includes the faucet, which I wrapped in a vinegar-soaked kitchen tissue – whereas my regular cleaning spray dribbled off. And rather than having to buy special tablets to clean my limescale-smothered glass kettle, I simply poured two tablespoons of concentrated vinegar inside and boiled it. As the limescale crackled off, it made a satisfying sizzling sound.

I wondered if vinegar had other advantages. Did it also kill off bacteria and other germs? And, importantly, was this simple, natural product better for the environment and for my health than regular cleaning products?

The internet is full of sustainability influencers and green cleaning blogs that advertise vinegar as a jack-of-all-trades and a safer and "greener" alternative to "toxic" cleaning products. These claims make sense on the surface; vinegar is after all just fermented alcohol and has long been used as a food preservative, in salad dressings, as well as a household cleaner – but I wanted evidence. After interviewing three experts, I learned that while some of these claims are true, the benefits of vinegar depend a lot on how it's used and the kind of grime you're trying to get rid of.

Reassuringly, Eric Beckman, a chemical engineer and emeritus professor at the University of Pittsburgh in Pennsylvania, told me that the best cleaning use for acetic acid – the main component of vinegar – is exactly what I had been using it for: as a descaler. Limescale – and rust, for that matter – consists of certain ions that dissolve more easily in acidic fluids like vinegar, he says. Beckman uses vinegar himself to get limescale off mirrors, while the microbiologist Dirk Bockmühl of Germany's Rhine-Waal University of Applied Sciences prefers using lemon juice, which contains citric acid, which he says is a more effective descaler and smells better. (Read more about why vinegar is such an effective cleaner.)

That said, vinegar doesn't work on everything. Beckman says that soap does a better job at removing oily films on dishes, while baking soda is effective against processed oils that have stuck onto surfaces while cooking. (Read more about whether baking soda is environmentally friendly).

However, Beckman expresses exasperation about a popular remedy of mixing vinegar together with baking soda. The mixture is chemically quite useless, he says, as the acid of vinegar and the base of baking soda effectively cancel each other out. "I use both, but not together," says Beckman. "Together, they give you nothing."

And while vinegar is often touted as a powerful antimicrobial, Bockmühl says, the truth is more nuanced. In a 2020 study, Bockmühl and his colleagues put vinegar to the test against a selection of disease-causing bacteria, viruses and fungi. While many internet recommendations suggest adding a dash of vinegar into a bucket of water for cleaning, Bockmühl found that its anti-microbial effects only kick in at an acetic acid concentration of 5% – its concentration in pure vinegar. And it was only fully effective at distilled concentrations of 10% – to which the researchers added a dash of citric acid – in killing off five common bacteria, including Escherichia coli and Staphylococcus aureus, as well as a mould, a yeast and a weakened........

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